Q5(a)(i). Fluorescence
Explain the following briefly: (i) Fluorescence
Answer in brief
Fluorescence is the emission of light when an excited molecule returns from the lowest excited singlet S₁ to the ground singlet S₀: spin-allowed, fast (within a few nanoseconds), so it stops almost as soon as the exciting light is cut off; the emitted light has a longer wavelength than the absorbed light.
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All parts of Question 5
- 5(a)(i) Fluorescence5 marks
- 5(a)(ii) Chemiluminescence5 marks
- 5(b)(i) Chelate effect5 marks
- 5(b)(ii) Lability5 marks
- 5(c)(i) Actinide spectra and the ligand5 marks
- 5(c)(ii) Co²⁺ salts stable, Co²⁺ complexes easily oxidised5 marks
- 5(d)(i) Shapes of the d orbitals5 marks
- 5(d)(ii) Splitting of d orbitals in a square-planar field5 marks