Q7(c). Platinum–alkyne bonding
In [Pt⁰(η²-PhC≡CPh)(PPh₃)₂], the C–C bond length is 1.32 Å and C–C–Ph bond angle is 140°. Write the structure and justify the bonding.
Model answer
The free solution for 2023 answers questions 1, 2, 4, 5 and 6, the ones picked in its time plan. Question 7 is answered in full in the IFoS Chemistry Paper I, 2021 to 2025 book, with every part of every paper.
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UPSC Indian Forest Service (Main) Chemistry Paper I: Model Answers 2021 to 2025
- All eight questions of each paper, with the question printed above its answer
- Physical chemistry numericals worked with units; inorganic structures drawn
- Topic-wise weightage and a topic-wise index
CoversDewar–Chatt–Duncanson modelplatinum alkyne complexπ back-bondingmetallacyclopropenediphenylacetylene
All parts of Question 7
- 7(a) Cytochrome P450 and its active oxidant15 marks
- 7(b) Structure of dimanganese decacarbonyl15 marks
- 7(c) Platinum–alkyne bonding10 marks