Indian Forest Service (Mains), Chemistry optional · 2025 · Paper I
Q3(a)(i). BCC edge length from diffraction
Question
A BCC solid gives a first-order X-ray reflection (λ = 0.154 nm) from (200) at 16.1°. Calculate the cell edge. Given sin 16.1° = 0.2773.
Answer in brief
The cell edge is 0.5554 nm.
Part of VKC Basic
Read the key points and the full model answer with VKC Basic
VKC Basic (₹999 for 6 months) opens every solved answer, the notes, the handbook and the daily answer archive. Every Mains test series includes it.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.
The handwritten model answer pages open with the VKC plan.
CoversBragg's lawBCC latticeinterplanar spacing d_hklMiller indicesX-ray diffraction
All parts of Question 3
- 3(a)(i) BCC edge length from diffraction5 marks
- 3(a)(ii) NaCl unit cell and Avogadro constant10 marks
- 3(b)(i) Composition after hydrogen leakage5 marks
- 3(b)(ii) Entropy change along two paths10 marks
- 3(c) Three-state nuclear-spin partition function10 marks