Indian Forest Service (Mains), Chemistry optional · 2022 · Paper II
Q7(b). Tautomers and chromophores
Question
Draw the tautomers of but-3-en-2-one and identify their chromophoric and auxochromic groups.
Answer in brief
The keto form is CH₃COCH=CH₂; methyl-side enolization gives CH₂=C(OH)CH=CH₂.
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Coversketo–enol tautomerismchromophoreauxochromebut-3-en-2-oneUV transitions
All parts of Question 7
- 7(a) Woodward–Fieser calculations10 marks
- 7(b) Tautomers and chromophores5 marks
- 7(c) ESR of pyrazine5 marks
- 7(d) Infrared distinctions10 marks
- 7(e) Lead tetraacetate cyclization of butanol10 marks