Indian Forest Service (Mains), Chemistry optional · 2023 · Paper II
Q8(e). Identification of glutaric anhydride
Question
Assign C₅H₆O₃: MS m/z 114, 76, 73, 60, 55; IR 2981, 1850, 1758, 1250 cm⁻¹; ¹H NMR δ 2.43 (t, 4H), 1.96 (pentet, 2H); ¹³C NMR 177, 33, 19.6 ppm.
Model answer
The free solution for 2023 answers questions 1, 2, 5, 6 and 7, the ones picked in its time plan. This part is not answered on the site yet. New answers are announced on Telegram.
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Coversglutaric anhydridestructure elucidationanhydride IR doublet¹³C NMRcombined spectroscopy
All parts of Question 8
- 8(a) Selective epoxidation and carbonyl rearrangement10 marks
- 8(b) A C9H12 alkylbenzene mass spectrum5 marks
- 8(c) Benzene radical anion5 marks
- 8(d) Average repeat-unit mass of a terpolymer5 marks
- 8(e) Identification of glutaric anhydride15 marks