Indian Forest Service (Mains), Chemistry optional · 2024 · Paper II
Q8(a)(ii). IR-active vibrations
Question
Which of CH₃OH, CH₃NH₂, CO₂, CH₄ and CO are infrared active?
Answer in brief
All five possess IR-active vibrational modes. A permanent molecular dipole is not required.
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CoversIR selection ruleIR active vibrationschange in dipole momentCO2 normal modesmethane IR
All parts of Question 8
- 8(a)(i) Axial versus equatorial alpha chlorine5 marks
- 8(a)(ii) IR-active vibrations5 marks
- 8(b) Mass spectra of benzyl alcohol and anisole10 marks
- 8(c)(i) NMR distinction of two isomer pairs10 marks
- 8(c)(ii) Structure from an aldol-condensation spectrum10 marks