Q3(d). Regioselective ketone alkylation
Identify thermodynamic A and kinetic B after base then MeI [from butan-2-one, as shown in the paper]; specify base, solvent, temperature and mechanism.
Answer in brief
A = 3-methylbutan-2-one; B = pentan-3-one.
Part of VKC Basic
Read the key points and the full model answer with VKC Basic
VKC Basic (₹999 for 6 months) opens every solved answer, the notes, the handbook and the daily answer archive. Every Mains test series includes it.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.
Coverskinetic vs thermodynamic enolateLDAenolate alkylationbutan-2-one methylationregioselectivity
All parts of Question 3
- 3(a) Stevens rearrangements of two ylides10 marks
- 3(b) Knoevenagel condensation10 marks
- 3(c) Erlenmeyer–Plöchl azlactone synthesis10 marks
- 3(d) Regioselective ketone alkylation10 marks