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UPSC Civil Services (Mains)

Chemistry optional

  • 2 papers
  • 250 marks each
  • 3 h per paper
  • 5 of 8 questions, Q1 and Q5 compulsory

Paper I covers physical and inorganic chemistry.

UPSC Civil Services (Mains), Chemistry optional · 2022 · Paper I

Q3(c). Speed distribution curves of argon and helium

Question

[Graph of relative number of molecules against molecular speed, showing Curve 1 and Curve 2, given in the paper.] The graph shows the distribution of molecular speeds for argon and helium at the same temperature. (i) Which curve, 1 or 2, better represents the behaviour of argon? (ii) Which curve represents the gas that effuses more slowly? (iii) Which curve more closely represents the behaviour of fluorine gas? Explain.

Answer in brief

(i) Curve 1 is argon (curve 2 is helium). (ii) Curve 1, argon, effuses more slowly. (iii) Curve 1: F₂ (M = 38.0) has almost the same molar mass as argon (M = 39.95).

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As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversMaxwell–Boltzmann distributionmost probable speedGraham's law of effusionmolecular speedkinetic theory of gases