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UPSC Civil Services (Mains)

Chemistry optional

  • 2 papers
  • 250 marks each
  • 3 h per paper
  • 5 of 8 questions, Q1 and Q5 compulsory

Paper I covers physical and inorganic chemistry.

UPSC Civil Services (Mains), Chemistry optional · 2023 · Paper I

Q6(d). Rubredoxin and how it differs from ferredoxins

Question

Explain the structural and other features of rubredoxin. How does it differ from ferredoxins?

Answer in brief

Rubredoxin is the simplest iron–sulfur protein: one Fe held tetrahedrally by four cysteine S atoms with no sulfide; ferredoxins contain Fe₂S₂ or Fe₄S₄ clusters bridged by sulfide and work at much more negative potentials.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversrubredoxinferredoxiniron–sulfur proteinsFe4S4 clusterbioinorganic chemistryelectron transfer