UPSC Civil Services (Mains), Chemistry optional · 2024 · Paper I
Q2(c)(i). Limiting radius ratio for coordination numbers 3 and 6
Question
Calculate the limiting radius ratio for the crystals with coordination number 3 and 6.
Answer in brief
Coordination number 3: r⁺/r⁻ = 2/√3 − 1 = 0.155; coordination number 6: r⁺/r⁻ = √2 − 1 = 0.414.
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Coverslimiting radius ratiocoordination numbertrigonal planaroctahedral voidrock-salt structure
All parts of Question 2
- 2(a) Uncertainty principle; orthogonality of ψ₁ and ψ₂ in a box10 marks
- 2(b)(i) Bond order of O₂, O₂⁻, O₂²⁻ and O₂⁺10 marks
- 2(b)(ii) Molecular orbital diagram of CO10 marks
- 2(c)(i) Limiting radius ratio for coordination numbers 3 and 610 marks
- 2(c)(ii) Stoichiometric defects10 marks