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UPSC Civil Services (Mains)

Chemistry optional

  • 2 papers
  • 250 marks each
  • 3 h per paper
  • 5 of 8 questions, Q1 and Q5 compulsory

Paper I covers physical and inorganic chemistry.

UPSC Civil Services (Mains), Chemistry optional · 2024 · Paper I

Q2(c)(i). Limiting radius ratio for coordination numbers 3 and 6

Question

Calculate the limiting radius ratio for the crystals with coordination number 3 and 6.

Answer in brief

Coordination number 3: r⁺/r⁻ = 2/√3 − 1 = 0.155; coordination number 6: r⁺/r⁻ = √2 − 1 = 0.414.

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The full model answer

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Coverslimiting radius ratiocoordination numbertrigonal planaroctahedral voidrock-salt structure