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UPSC Civil Services (Mains)

Chemistry optional

  • 2 papers
  • 250 marks each
  • 3 h per paper
  • 5 of 8 questions, Q1 and Q5 compulsory

Paper I covers physical and inorganic chemistry.

UPSC Civil Services (Mains), Chemistry optional · 2024 · Paper I

Q8(b)(ii). Structure and bonding of B₂H₆

Question

Draw the structure of B₂H₆. Explain the bonding in B₂H₆ on the basis of the hybridization approach.

Answer in brief

B₂H₆ has two BH₂ groups joined by two B–H–B bridges; each boron is sp³ hybridised, the four terminal B–H bonds are two-electron bonds and each bridge is a three-centre two-electron bond.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversdiboranethree-centre two-electron bondbanana bondelectron-deficient compoundssp³ hybridisation