Q8(b)(ii). Structure and bonding of B₂H₆
Draw the structure of B₂H₆. Explain the bonding in B₂H₆ on the basis of the hybridization approach.
Answer in brief
B₂H₆ has two BH₂ groups joined by two B–H–B bridges; each boron is sp³ hybridised, the four terminal B–H bonds are two-electron bonds and each bridge is a three-centre two-electron bond.
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Coversdiboranethree-centre two-electron bondbanana bondelectron-deficient compoundssp³ hybridisation
All parts of Question 8
- 8(a) Why all F atoms of PF₅ look alike in the ¹⁹F NMR spectrum10 marks
- 8(b)(i) Possible arrangements and shape of ClF₃10 marks
- 8(b)(ii) Structure and bonding of B₂H₆10 marks
- 8(c) Principles of four methods of separating the lanthanides20 marks