VKC ScienceChemistry for written exams Telegram

UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2016 · Mains Paper I

Q1(g). Packing fraction

Question

Explain packing fraction.

Answer in brief

In nuclear chemistry, packing fraction is the fractional difference between isotopic mass and mass number: f=(M-A)/A, often tabulated as 10⁴f.

Key points

  • M is the numerical isotopic atomic mass in unified atomic mass units and A is the integer mass number.
  • Positive f means M>A; negative f means M<A. It measures mass excess per nucleon relative to the mass-number reference.
  • It is not the same as mass defect relative to separated protons and neutrons; binding energy is calculated from that mass defect.
  • In solid-state chemistry the same phrase denotes the fraction of a unit cell occupied by hard spheres: APF=n(4π r³/3)/a³.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(g), 2016 Mains Paper I: solution pages 3 and 4
Solution pages 3 and 4 of 17

CoversPacking fractionNuclear chemistry / solid state