UPSC Combined Geo-Scientist, Mains · 2017 · Mains Paper I
Q1(g). CFCs and ozone depletion
Question
Nowadays CFC (Chlorofluorocarbon)-free refrigerators are promoted in the market. Why and what is the consequence upon release of CFCs to the atmosphere? [Write only relevant reactions]
Answer in brief
CF₂Cl₂ →[hν] CF₂Cl• + Cl•
Key points
- Cl• + O₃ → ClO• + O₂
- ClO• + O → Cl• + O₂
- Net: O₃ + O → 2O₂.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

CoversCFCsozone depletionEnvironmental chemistry
All parts of Question 1
- 1(a) Dichromate oxidation of iron5 marks
- 1(b) Phosphorus-doped silicon5 marks
- 1(c) Nickel magnetic moment5 marks
- 1(d) Eighteen-electron counts5 marks
- 1(e) Magic numbers5 marks
- 1(f) Dimethylberyllium bridges5 marks
- 1(g) CFCs and ozone depletion5 marks
- 1(h) Why thorium and uranium are well studied5 marks
- 1(i) Average and individual oxidation states5 marks
- 1(j) Mo and W radii5 marks