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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2018 · Mains Paper I

Q11(a). Ce and Yb magnetic moments

Question

Calculate the magnetic moment of Ce³⁺ (f¹) and Yb³⁺ (f¹³) considering spin-orbit coupling. Comment on the difference (if any) in the ground State terms and values of the moment, of the two ions.

Answer in brief

Ce(III): ²F_(5/2), μ=2.54μ_B; Yb(III): ²F_(7/2), μ=4.54μ_B.

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CoversYb magnetic momentsSpin–orbit coupling in lanthanides

All parts of Question 11