VKC ScienceChemistry for written exams Telegram

UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper I

Q10(b). Praseodymium magnetic moment

Question

Calculate magnetic moment of Pr₂(SO₄)₃·8H₂O and compare it with spin-only value. Justify the observed deviation. (Atomic number of Pr is 59)

Answer in brief

Each Pr(III) ion has free-ion moment 3.58μ_B, compared with the spin-only value 2.83μ_B.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversPraseodymium magnetic momentLanthanide magnetism

All parts of Question 10