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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper I

Q4(a). Broad asymmetric copper band

Question

Electronic spectrum of [Cu(H₂O)₆]²⁺ shows unsymmetric broad band. Justify.

Answer in brief

Jahn–Teller splitting of the d⁹ levels produces overlapping transitions; vibrational and solvent broadening merge them into an asymmetric envelope.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversBroad asymmetric copper bandJahn–Teller distortion and spectra

All parts of Question 4