UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper I
Q4(a). Broad asymmetric copper band
Question
Electronic spectrum of [Cu(H₂O)₆]²⁺ shows unsymmetric broad band. Justify.
Answer in brief
Jahn–Teller splitting of the d⁹ levels produces overlapping transitions; vibrational and solvent broadening merge them into an asymmetric envelope.
Part of VKC Basic
Read the key points and the full model answer with VKC Basic
VKC Basic (₹999 for 6 months) opens every solved answer, the notes, the handbook and the daily answer archive. Every Mains test series includes it.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.
The handwritten model answer pages open with the VKC plan.
CoversBroad asymmetric copper bandJahn–Teller distortion and spectra
All parts of Question 4
- 4(a) Broad asymmetric copper band15 marks
- 4(b) Nickel ligand-field parameters15 marks