UPSC Combined Geo-Scientist, Mains · 2022 · Mains Paper I
Q1(i). Carbon-14 dating of wood
Question
What is Carbon-14 dating? Why is this method used to determine the age of the ancient articles made of wood?
Answer in brief
Radiocarbon dating estimates time since carbon exchange ceased from the remaining ¹⁴C activity. Wood retains carbon fixed by a living tree and becomes a decay clock after death.
Key points
- Atmospheric ¹⁴C forms mainly by ¹⁴N(n,p)¹⁴C and enters CO₂. Photosynthesis incorporates this carbon into growing wood.
- During life, exchange with the environment maintains a carbon-isotope ratio related to the surroundings. After death, further exchange largely stops.
- ¹⁴C undergoes β⁻ decay: ¹⁴C → ¹⁴N + e⁻ + antineutrino. The conventional physical half-life is about 5730 years.
- With initial and present specific activities A₀ and A, t = (t₁/₂/ln 2) ln(A₀/A).
- Contamination, changes in atmospheric ¹⁴C and old wood affect the result; calendar dates require calibration.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Coverscarbon-14 datingradiocarbon datinghalf-life 5730 yearsbeta decayage of wood
All parts of Question 1
- 1(a) Minerals and framework structures5 marks
- 1(b) Ground terms by L-S coupling5 marks
- 1(c) Square-planar stereoisomers5 marks
- 1(d) Carbonate in carbonic acid5 marks
- 1(e) Chloride from silver chloride5 marks
- 1(f) Iron percentage by permanganate5 marks
- 1(g) Masking copper to determine nickel5 marks
- 1(h) Carbonyl ligand counts5 marks
- 1(i) Carbon-14 dating of wood5 marks
- 1(j) Oxidising power across the series5 marks