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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2022 · Mains Paper I

Q11(b). Using magnetism to distinguish spin states

Question

How is magnetic data useful to distinguish between strong field and weak field octahedral complexes of d¹ to d⁹ metals?

Answer in brief

Spin-only moments distinguish high- and low-spin octahedral d⁴–d⁷ configurations. For d¹–d³ and d⁸–d⁹, the unpaired-electron counts are the same in both field regimes.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversmagnetic momenthigh spin low spinstrong field weak fieldspin-only formulamagnetic susceptibility

All parts of Question 11