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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2022 · Mains Paper I

Q8(c). Metal-ion indicators in EDTA titrations

Question

Explain the metal ion-indicator-EDTA reactions. What are the important criteria to be satisfied by metal ion indicator for visual detection of end points?

Answer in brief

The indicator forms a coloured metal complex. Near equivalence EDTA displaces the indicator, exposing its contrasting free colour; the metal-EDTA complex must be sufficiently more stable.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversmetallochromic indicatorEriochrome Black TEDTA titration end pointmetal ion indicator criteria

All parts of Question 8