Q5(c). Magnetite from an ignited iron oxide residue
An ore containing magnetite, Fe₃O₄, was analyzed by dissolving a 1.500 g sample in conc. HCl giving a mixture of Fe²⁺ and Fe³⁺. After adding HNO₃ to oxidize any Fe²⁺ to Fe³⁺, the resulting solution was diluted with water and Fe³⁺ precipitated as Fe(OH)₃ by adding NH₃. After filtering and rinsing, the residue was ignited giving 0.8525 g of pure Fe₂O₃. Calculate the % w/w Fe₃O₄ in the solution. [Given: FW of Fe₂O₃ = 159.69 g/mol and FW of Fe₃O₄ = 231.54 g/mol]
Answer in brief
The Fe₃O₄-equivalent content of the original ore is 54.94% w/w.
Part of VKC Basic
Read the key points and the full model answer with VKC Basic
VKC Basic (₹999 for 6 months) opens every solved answer, the notes, the handbook and the daily answer archive. Every Mains test series includes it.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.
Coversgravimetric factormagnetite analysisFe2O3 ignitioniron gravimetryFe(OH)3 precipitation
All parts of Question 5
- 5(a) A face-capped trinickel carbonyl cluster10 marks
- 5(b) Balancing nuclear capture products10 marks
- 5(c) Magnetite from an ignited iron oxide residue10 marks