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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper I

Q5(c). Magnetite from an ignited iron oxide residue

Question

An ore containing magnetite, Fe₃O₄, was analyzed by dissolving a 1.500 g sample in conc. HCl giving a mixture of Fe²⁺ and Fe³⁺. After adding HNO₃ to oxidize any Fe²⁺ to Fe³⁺, the resulting solution was diluted with water and Fe³⁺ precipitated as Fe(OH)₃ by adding NH₃. After filtering and rinsing, the residue was ignited giving 0.8525 g of pure Fe₂O₃. Calculate the % w/w Fe₃O₄ in the solution. [Given: FW of Fe₂O₃ = 159.69 g/mol and FW of Fe₃O₄ = 231.54 g/mol]

Answer in brief

The Fe₃O₄-equivalent content of the original ore is 54.94% w/w.

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Coversgravimetric factormagnetite analysisFe2O3 ignitioniron gravimetryFe(OH)3 precipitation

All parts of Question 5