UPSC Combined Geo-Scientist, Mains · 2016 · Mains Paper III
Q10(b). Aromatic ammonium ylide
Question
Predict the initial product when 1-(trialkylammonio)indene, bearing H at C1, is treated with hydroxide.
Answer in brief
Deprotonation at C1 gives an indenyl-stabilised ammonium ylide.
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CoversAromatic ammonium ylideReactive intermediates
All parts of Question 10
- 10(a) Electrocyclic stereochemistry5 marks
- 10(b) Aromatic ammonium ylide5 marks
- 10(c) Benzyne generation and trapping5 marks