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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper III covers analytical and organic chemistry.

UPSC Combined Geo-Scientist, Mains · 2018 · Mains Paper III

Q1(f). ICP multielement capability

Question

Why is ICP better suited to multielement analysis than flame atomic absorption?

Answer in brief

An ICP excites or ionises many elements simultaneously, whereas conventional flame AAS usually measures element-specific absorption sequentially.

Key points

  • The hot argon plasma atomises a wide range of species and supplies many emission lines (ICP-OES) or ions (ICP-MS).
  • Multichannel optical detection or rapid mass scanning measures many elements from one sample introduction.
  • Flame AAS generally requires a suitable source and wavelength for each element and may require different flame conditions.
  • ICP offers wide dynamic range and fewer refractory-compound problems, though spectral overlaps, matrix effects and calibration still need control.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(f), 2018 Mains Paper III: solution pages 3 and 4
Solution pages 3 and 4 of 20

CoversICP multielement capabilityAtomic spectroscopy