UPSC Combined Geo-Scientist, Mains · 2018 · Mains Paper III
Q7(b). Substituted aniline basicity
Question
Order the para-substituted anilines: (i) nitro, (ii) methoxy, (iii) cyano and (iv) methyl, by decreasing basicity.
Answer in brief
(ii) > (iv) > (iii) > (i).
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CoversSubstituted aniline basicityElectronic effects
All parts of Question 7
- 7(a) Epoxidation reactivity5 marks
- 7(b) Substituted aniline basicity5 marks
- 7(c)(i) Dakin oxidation5 marks
- 7(c)(ii) Successive Claisen rearrangements5 marks
- 7(d) Unsymmetrical benzil synthesis5 marks
- 7(e) Bucherer amination5 marks