UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper III
Q7(a). Grignard homologation
Question
Benzyl chloride is treated with Mg/ether, formaldehyde and then H₂O/H⁺. Identify intermediates and give mechanisms of the last two steps.
Answer in brief
The sequence gives benzylmagnesium chloride, its formaldehyde-addition alkoxide, then 2-phenylethanol.
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CoversGrignard homologationOrganometallic synthesis
All parts of Question 7
- 7(a) Grignard homologation10 marks
- 7(b) Pentane-isomer melting points5 marks
- 7(c) Gabriel route to proline10 marks
- 7(d) IR activity of alkene stretches5 marks