UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper III
Q2(b). Extraction of metal chelates
Question
Derive the dependence of metal-chelate extraction on pH and extractant concentration.
Answer in brief
For an ideal neutral chelate, D≈ Kₑₓ[HR]_(org)ⁿ/[H⁺]ⁿ; raising pH generally promotes extraction.
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CoversExtraction of metal chelatesSolvent extraction
All parts of Question 2
- 2(a) Uncertainty in solubility5 marks
- 2(b) Extraction of metal chelates10 marks
- 2(c) Stoichiometry of the iron–phenanthroline complex10 marks
- 2(d) Calibration of TGA5 marks