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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper III covers analytical and organic chemistry.

UPSC Combined Geo-Scientist, Mains · 2023 · Mains Paper III

Q10(c). Cope rearrangement of cis-2,3-divinyloxirane

Question

Identify the product Y for the thermal sigmatropic reaction of X (Δ). Name the reaction and give suitable mechanism. [Structure of X given in the paper]

Answer in brief

Cope rearrangement ([3,3]-sigmatropic shift). Y = 4,5-dihydrooxepine, C₆H₈O.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversCope rearrangement[3,3]-sigmatropic shiftdivinyloxiranedihydrooxepineboat transition state