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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper III covers analytical and organic chemistry.

UPSC Combined Geo-Scientist, Mains · 2026 · Mains Paper III

Q5(b). Distribution ratio of an organic acid at three pH values

  • 10 marks
  • Topic: Solvent extraction
  • Question only
Question

An organic acid dissolved in 50 mL of water is equilibrated with 50 mL of ether. The distribution coefficient (K_D) is 50 and the dissociation constant (Kₐ) is 5.0×10⁻⁵. Calculate the distribution ratio (D), if the aqueous layer is at pH 3, pH 5 and pH 7.

Model answer

The free solution for 2026 answers the questions picked in its time plan. Question 5 is answered in full in the Book Edition of the 2026 solutions of Geo-Scientist Chemistry Paper III.

Coversdistribution ratioDistribution ratio of an organic acid at three pH values

All parts of Question 5