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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q112 of 120

Geo-Scientist Prelims 2020 Chemistry Q112: The major product(s) formed in the following reaction is/are:

QuestionOrganic / benzyne mechanism

The major product(s) formed in the following reaction is/are:

UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q112: figure printed with the question
UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q112: answer options as printed
  1. (a) o-Toluidine only
  2. (b) 2-Bromo-3-methylaniline
  3. (c) m-Toluidine only
  4. (d) o-Toluidine + m-toluidine

Answer: (a)

NaNH₂/liq. NH₃ on o-bromotoluene goes by elimination–addition (benzyne): 3-methylbenzyne forms and NH₂⁻ adds to either end. Strictly this gives a mixture of o- and m-toluidine (option d). UPSC's key holds (a).

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