QuestionSolid state / defects
The appearance of colour in solid alkali metal halides is generally due to:
- (a) Schottky defect
- (b) Frenkel defect
- (c) Interstitial Position
- (d) F-Centres
Answer: (d) F-Centres
Heating alkali halides in alkali vapour gives metal-excess defect: anion vacancies trap electrons = F-centres (Farbenzentren). They absorb visible light: NaCl yellow, KCl violet, LiCl pink → (d).