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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q14 of 120

Geo-Scientist Prelims 2020 Chemistry Q14: The appearance of colour in solid alkali metal halides is generally…

QuestionSolid state / defects

The appearance of colour in solid alkali metal halides is generally due to:

  1. (a) Schottky defect
  2. (b) Frenkel defect
  3. (c) Interstitial Position
  4. (d) F-Centres

Answer: (d) F-Centres

Heating alkali halides in alkali vapour gives metal-excess defect: anion vacancies trap electrons = F-centres (Farbenzentren). They absorb visible light: NaCl yellow, KCl violet, LiCl pink → (d).

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