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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q24 of 120

Geo-Scientist Prelims 2020 Chemistry Q24: Which one of the following is the IUPAC name of the complex…

QuestionCoordination / nomenclature

Which one of the following is the IUPAC name of the complex K₃[Fe(CN)₆]?

  1. (a) Potassium hexacyanoferrate(II)
  2. (b) Potassium hexacyanoferrate(III)
  3. (c) Trispotassium hexacyanoiron(III)
  4. (d) Potassium hexacyanoiron(III)

Answer: (b) Potassium hexacyanoferrate(III)

K₃[Fe(CN)₆]: anion charge −3; 6 CN⁻ = −6 → Fe = +3. Anionic complex → metal ends in -ate, iron → ferrate. Name: potassium hexacyanoferrate(III) → (b). (Ferrate(II) is K₄[Fe(CN)₆].)

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