QuestionCoordination / nomenclature
Which one of the following is the IUPAC name of the complex K₃[Fe(CN)₆]?
- (a) Potassium hexacyanoferrate(II)
- (b) Potassium hexacyanoferrate(III)
- (c) Trispotassium hexacyanoiron(III)
- (d) Potassium hexacyanoiron(III)
Answer: (b) Potassium hexacyanoferrate(III)
K₃[Fe(CN)₆]: anion charge −3; 6 CN⁻ = −6 → Fe = +3. Anionic complex → metal ends in -ate, iron → ferrate. Name: potassium hexacyanoferrate(III) → (b). (Ferrate(II) is K₄[Fe(CN)₆].)