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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q31 of 120

Geo-Scientist Prelims 2020 Chemistry Q31: Consider the following hydroxides:

Questions-block / hydroxides

Consider the following hydroxides:

  1. Be(OH)₂
  2. Sr(OH)₂
  3. Mg(OH)₂
  4. Ba(OH)₂

The correct order of basicity of the above hydroxides will be:

  1. (a) Sr(OH)₂ < Be(OH)₂ < Ba(OH)₂ < Mg(OH)₂
  2. (b) Be(OH)₂ < Mg(OH)₂ < Ba(OH)₂ < Sr(OH)₂
  3. (c) Mg(OH)₂ < Ba(OH)₂ < Sr(OH)₂ < Be(OH)₂
  4. (d) Be(OH)₂ < Mg(OH)₂ < Sr(OH)₂ < Ba(OH)₂

Answer: (d) Be(OH)₂ < Mg(OH)₂ < Sr(OH)₂ < Ba(OH)₂

Down group 2, ionisation energy falls and M–OH bond becomes more ionic → basicity rises: Be(OH)₂ (amphoteric) < Mg(OH)₂ < Sr(OH)₂ < Ba(OH)₂ → (d). Solubility also rises down the group.

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