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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q45 of 120

Geo-Scientist Prelims 2020 Chemistry Q45: The root mean square velocity of a monoatomic gas of molar mass ‘M’…

QuestionKinetic theory / rms speed

The root mean square velocity of a monoatomic gas of molar mass ‘M’ (g mol⁻¹) is ‘u’. What is the correct relation between ‘u’ and average kinetic energy (E) per mole?

  1. (a) u = \(\sqrt{\frac{3E}{M}}\)
  2. (b) u = \(\sqrt{\frac{2E}{3M}}\)
  3. (c) u = \(\sqrt{\frac{2E}{M}}\)
  4. (d) u = \(\sqrt{\frac{E}{3M}}\)

Answer: (c) u = \(\sqrt{\frac{2E}{M}}\)

Per mole, average KE E = ½ M u² (u = rms speed, M = molar mass). So u = √(2E/M) → (c). Check: E = (3/2)RT gives u = √(3RT/M), the usual form.

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