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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q50 of 120

Geo-Scientist Prelims 2020 Chemistry Q50: The latent heat of vaporization of Br₂ at 59˚C and at 1 atm…

QuestionThermodynamics / ΔH and ΔU

The latent heat of vaporization of Br₂ at 59˚C and at 1 atm pressure is 29.2 kJ mol⁻¹. The value of ∆U would be: (R = 8.314 × 10⁻³ kJ mol⁻¹ K⁻¹)

  1. (a) 26.44 kJ mol⁻¹
  2. (b) 2.644 kJ mol⁻¹
  3. (c) 264.4 kJ mol⁻¹
  4. (d) 31.96 kJ mol⁻¹

Answer: (a) 26.44 kJ mol⁻¹

Br₂(l) → Br₂(g), Δn(g) = 1, T = 332 K. ΔU = ΔH − ΔnRT = 29.2 − 8.314 × 10⁻³ × 332 = 29.2 − 2.76 = 26.44 kJ mol⁻¹ → (a).

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