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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q54 of 120

Geo-Scientist Prelims 2020 Chemistry Q54: For N₂(g) + 3H₂(g) ⇋ 2 NH₃(g), the expression for ∆H is:

QuestionThermodynamics / ΔH and ΔU

For N₂(g) + 3H₂(g) ⇋ 2 NH₃(g), the expression for ∆H is:

  1. (a) ∆U + 2 RT
  2. (b) ∆U + RT
  3. (c) ∆U – 2 RT
  4. (d) ∆U – RT

Answer: (c) ∆U – 2 RT

ΔH = ΔU + Δn(g)RT. Δn(g) = 2 − (1 + 3) = −2 → ΔH = ΔU − 2RT → (c).

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