QuestionElectrochemistry / dilution
What will be the effect of dilution on specific and equivalent conductance of an aqueous solution of a strong electrolyte?
- (a) The specific conductance decreases and equivalent conductance increases
- (b) The specific conductance increases and equivalent conductance decreases
- (c) Both will increase
- (d) Both will decrease
Answer: (a) The specific conductance decreases and equivalent conductance increases
On dilution: κ (specific conductance) decreases — fewer ions per cm³. Λ (equivalent/molar) increases — interionic attraction falls and Λ = κ × 1000/c → (a).