VKC ScienceChemistry for written exams Telegram

UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q77 of 120

Geo-Scientist Prelims 2020 Chemistry Q77: The specific conductance of 0.01 M solution of acetic acid was…

QuestionElectrochemistry / degree of dissociation

The specific conductance of 0.01 M solution of acetic acid was found to be 0.015 S m⁻¹ at 25˚C. Molar conductance of acetic acid at infinite dilution is 400 × 10⁻⁴ S m² mol⁻¹. The degree of dissociation of acetic acid will be:

  1. (a) 0.375
  2. (b) 0.0375
  3. (c) 0.00375
  4. (d) 0.357

Answer: (b) 0.0375

Λm = κ/c = 0.015 S m⁻¹ / 10 mol m⁻³ = 1.5 × 10⁻³ S m² mol⁻¹. α = Λm/Λ°m = 1.5 × 10⁻³ / 400 × 10⁻⁴ = 0.0375 → (b). Trap: 0.01 M = 10 mol m⁻³.

Take this paper offlineAll 120 questions with answers and explanations in one PDF.
Download PDFJoin Telegram