QuestionOrganic / aromaticity
Which one of the following structures is non-aromatic?

- (a) Naphthalene
- (b) Cyclopentadienyl anion
- (c) Cyclodecapentaene ([10]annulene)
- (d) Phenanthrene
Answer: (c)
Naphthalene (10π) and phenanthrene (14π) are aromatic; cyclopentadienyl anion (6π) is aromatic. [10]Annulene (cyclodecapentaene) cannot be planar — inner H atoms clash (or angle strain) — so it is non-aromatic → (c).