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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q82 of 120

Geo-Scientist Prelims 2020 Chemistry Q82: Which one of the following structures is non-aromatic?

QuestionOrganic / aromaticity

Which one of the following structures is non-aromatic?

UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q82: answer options as printed
  1. (a) Naphthalene
  2. (b) Cyclopentadienyl anion
  3. (c) Cyclodecapentaene ([10]annulene)
  4. (d) Phenanthrene

Answer: (c)

Naphthalene (10π) and phenanthrene (14π) are aromatic; cyclopentadienyl anion (6π) is aromatic. [10]Annulene (cyclodecapentaene) cannot be planar — inner H atoms clash (or angle strain) — so it is non-aromatic → (c).

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