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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q89 of 120

Geo-Scientist Prelims 2020 Chemistry Q89: Which one of the following molecules does NOT have a plane of…

QuestionStereochemistry / symmetry elements

Which one of the following molecules does NOT have a plane of symmetry?

UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q89: answer options as printed
  1. (a) 3,4-Dichlorohexane (sawhorse form)
  2. (b) 3,4-Dichlorohexane (zigzag, both Cl wedged)
  3. (c) 1,3-Dichlorocyclobutane (one Cl wedge, one dash)
  4. (d) 1,2,3-Trimethylcyclopropane (one Me dash, two wedged)

Answer: (b)

(b) 3,4-dichlorohexane as drawn is (3S,4S) — a chiral (dl) form, so it has no plane of symmetry. (a) is the meso form, (c) trans-1,3-dichlorocyclobutane and (d) the trimethylcyclopropane have a mirror plane → (b).

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