Indian Forest Service (Mains), Chemistry optional · 2025 · Paper I
Q5(b). Langmuir adsorption isotherm
Question
State the assumptions of Langmuir adsorption and derive its isotherm.
Answer in brief
For monolayer adsorption on equivalent independent sites, θ = KP/(1 + KP) and v = vm KP/(1 + KP).
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CoversLangmuir adsorption isothermmonolayer adsorptionassumptions of Langmuir isothermfractional coverage θ
All parts of Question 5
- 5(a) Order from total-pressure measurements8 marks
- 5(b) Langmuir adsorption isotherm8 marks
- 5(c) Hexaamminechromium(III)8 marks
- 5(d) Dicobalt octacarbonyl8 marks
- 5(e) Reactions in nonaqueous media8 marks