Indian Forest Service (Mains), Chemistry optional · 2022 · Paper II
Q2(a). Two eliminations from a meso dibromide
Question
Give the products, stereochemistry and mechanisms for meso-2,3-dibromobutane with iodide ion and, separately, with ethoxide ion.
Model answer
The free solution for 2022 answers questions 1, 3, 5, 7 and 8, the ones picked in its time plan. This part is not answered on the site yet. New answers are announced on Telegram.
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Coversanti eliminationE2 stereochemistrymeso-2,3-dibromobutanedebromination by iodidedehydrobromination
All parts of Question 2
- 2(a) Two eliminations from a meso dibromide10 marks
- 2(b) Favorskii rearrangement of a dibromoketone10 marks
- 2(c) Rearrangement of a bornane alcohol10 marks
- 2(d) Claisen rearrangement of an allyl vinyl ether5 marks
- 2(e) Deuterium and hydrolysis rate5 marks