Indian Forest Service (Mains), Chemistry optional · 2022 · Paper II
Q5(d). CO bond length from rotational spacing
Question
Rotational lines of CO are separated by 3.84 cm⁻¹. Calculate its bond length.
Answer in brief
Taking ¹²C¹⁶O as a rigid rotor gives r ≈ 1.13 Å.
Part of VKC Basic
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The full model answer
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Coversrotational spectroscopyrigid rotorbond length of COrotational constant Bmicrowave spectrum
All parts of Question 5
- 5(a) Hydrophobic effect in biomolecules5 marks
- 5(b) Stopping radical styrene polymerization5 marks
- 5(c) Complementary DNA and RNA sequence5 marks
- 5(d) CO bond length from rotational spacing5 marks
- 5(e) Isotope shift of C–H stretching5 marks
- 5(f) Relative carbonyl stretching frequencies5 marks
- 5(g) Epoxide opening by dimethylamine5 marks
- 5(h) Labelled allylic bromination5 marks