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Indian Forest Service (Mains)

Chemistry optional

  • 2 papers
  • 200 marks each
  • 3 h per paper

Paper II covers organic chemistry and spectroscopy.

Indian Forest Service (Mains), Chemistry optional · 2023 · Paper II

Q2(b). Halohydrin cyclization and chair populations

Question

Rank the three drawn methylcyclohexane chlorohydrins I–III in decreasing tendency to form an epoxide. [structures of chlorohydrins I–III given in the paper]

Answer in brief

The expected order is II > I ≫ III.

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Coversepoxide formationhalohydrintrans-diaxial arrangementintramolecular SN2neighbouring group participationconformational analysis

All parts of Question 2