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Indian Forest Service (Mains)

Chemistry optional

  • 2 papers
  • 200 marks each
  • 3 h per paper

Paper II covers organic chemistry and spectroscopy.

Indian Forest Service (Mains), Chemistry optional · 2023 · Paper II

Q2(d). Butanone phenylhydrazone and Fischer cyclization

Question

Give the products of condensation of butan-2-one with phenylhydrazine, with mechanism.

Answer in brief

Condensation gives butan-2-one phenylhydrazone. Under the usual additional acidic Fischer conditions it can give 2,3-dimethylindole and 2-ethylindole.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversFischer indole synthesisphenylhydrazone2,3-dimethylindoleenehydrazine[3,3] sigmatropic rearrangement

All parts of Question 2