Indian Forest Service (Mains), Chemistry optional · 2025 · Paper II
Q4(b). Nucleophilic aromatic substitution
Question
Complete p-Z-nitrobenzene with cyanide and show the mechanism.
Answer in brief
If Z is a leaving group such as halogen, CN replaces Z to give 4-nitrobenzonitrile.
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Coversnucleophilic aromatic substitutionSNArMeisenheimer complex4-nitrobenzonitrileaddition–elimination
All parts of Question 4
- 4(a) Primary kinetic isotope effect10 marks
- 4(b) Nucleophilic aromatic substitution10 marks
- 4(c)(i) Acidity and aromatic conjugate bases5 marks
- 4(c)(ii) 1,2 versus 1,4 addition5 marks
- 4(d) Pyrrole with chloroform and base10 marks