Indian Forest Service (Mains), Chemistry optional · 2025 · Paper II
Q4(c)(i). Acidity and aromatic conjugate bases
Question
Rank the three displayed compounds in decreasing acidity. [structures of indene (I), fluorene (II) and a pentakis(trifluoromethyl)cyclopentadiene (III) given in the paper]
Answer in brief
III > I > II.
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Coversacidity of indene and fluorenecyclopentadienyl anionaromatic conjugate basepKaCF₃ inductive effect
All parts of Question 4
- 4(a) Primary kinetic isotope effect10 marks
- 4(b) Nucleophilic aromatic substitution10 marks
- 4(c)(i) Acidity and aromatic conjugate bases5 marks
- 4(c)(ii) 1,2 versus 1,4 addition5 marks
- 4(d) Pyrrole with chloroform and base10 marks