Q1(d). Uncertainty in the position of a honeybee
Use the Heisenberg uncertainty principle to calculate the uncertainty (in metres) in the position of a honeybee weighing 0.68 g and travelling at a velocity of 0.85 m/s. Assume that the uncertainty in the velocity is 0.1 m/s.
Answer in brief
Δ x≥7.76×10⁻³¹ m: immeasurably small, so the honeybee obeys classical mechanics.
Key points
- position and momentum along one axis cannot both be known exactly: Δ x Δ p≥(h)/(4π).
- Δ p=m Δ v=(6.8×10⁻⁴)(0.1)=6.8×10⁻⁵ kg m s⁻¹
- Δ x=(h)/(4π m Δ v)=6.627×10⁻³⁴4×3.1416×6.8×10⁻⁵, Δ x≥7.76×10⁻³¹ m
- the principle limits the spreads, not the values. (With the form Δ x Δ p≥ h/2π the answer is 1.55×10⁻³⁰ m; the conclusion is the same.)
The full model answer
Written out in full, as it should go in the answer booklet. The solution page with its diagrams follows it.
Given: m=0.68 g =6.8×10⁻⁴ kg; Δ v=0.1 m s⁻¹; h=6.627×10⁻³⁴ J s.
- Principle: position and momentum along one axis cannot both be known exactly: Δ x Δ p≥(h)/(4π).
- Δ p=m Δ v=(6.8×10⁻⁴)(0.1)=6.8×10⁻⁵ kg m s⁻¹
- Δ x=(h)/(4π m Δ v)=6.627×10⁻³⁴4×3.1416×6.8×10⁻⁵, Δ x≥7.76×10⁻³¹ m
- The velocity 0.85 m s⁻¹ does not enter: the principle limits the spreads, not the values. (With the form Δ x Δ p≥ h/2π the answer is 1.55×10⁻³⁰ m; the conclusion is the same.)
- Scale: 7.76×10⁻³¹ m is 10¹⁵ times smaller than a proton. No instrument can detect it, so the bee has a well-defined trajectory.
- Contrast: an electron (m=9.11×10⁻³¹ kg) with the same Δ v has Δ x=5.8×10⁻⁴ m, far larger than an atom. For electrons in atoms the principle replaces orbits by orbitals (probability distributions).
Application. the same relation sets the zero-point energy of a particle in a box and of a vibrating bond: confining a particle to a region Δ x forces a momentum spread and hence a minimum kinetic energy.
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All parts of Question 1
- 1(a)(i) Covalent character of NaBr and MgBr₂5 marks
- 1(a)(ii) Order of lattice energies: LiCl, KCl, KBr, MgBr₂5 marks
- 1(b) Naming the conformations of chelate rings10 marks
- 1(c) Internal pressure (∂ U/∂ V)_T of a van der Waals gas10 marks
- 1(d) Uncertainty in the position of a honeybee10 marks
- 1(e) Maxwell distribution of molecular speeds and the effect of temperature10 marks