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UPSC Civil Services (Mains)

Chemistry optional

  • 2 papers
  • 250 marks each
  • 3 h per paper
  • 5 of 8 questions, Q1 and Q5 compulsory

Paper I covers physical and inorganic chemistry.

UPSC Civil Services (Mains), Chemistry optional · 2019 · Paper I

Q1(d). Uncertainty in the position of a honeybee

  • 10 marks
  • Answered
Question

Use the Heisenberg uncertainty principle to calculate the uncertainty (in metres) in the position of a honeybee weighing 0.68 g and travelling at a velocity of 0.85 m/s. Assume that the uncertainty in the velocity is 0.1 m/s.

Answer in brief

Δ x≥7.76×10⁻³¹ m: immeasurably small, so the honeybee obeys classical mechanics.

Key points

  • position and momentum along one axis cannot both be known exactly: Δ x Δ p≥(h)/(4π).
  • Δ p=m Δ v=(6.8×10⁻⁴)(0.1)=6.8×10⁻⁵ kg m s⁻¹
  • Δ x=(h)/(4π m Δ v)=6.627×10⁻³⁴4×3.1416×6.8×10⁻⁵, Δ x≥7.76×10⁻³¹ m
  • the principle limits the spreads, not the values. (With the form Δ x Δ p≥ h/2π the answer is 1.55×10⁻³⁰ m; the conclusion is the same.)

The full model answer

Written out in full, as it should go in the answer booklet. The solution page with its diagrams follows it.

Given: m=0.68 g =6.8×10⁻⁴ kg; Δ v=0.1 m s⁻¹; h=6.627×10⁻³⁴ J s.

  1. Principle: position and momentum along one axis cannot both be known exactly: Δ x Δ p≥(h)/(4π).
  2. Δ p=m Δ v=(6.8×10⁻⁴)(0.1)=6.8×10⁻⁵ kg m s⁻¹
  3. Δ x=(h)/(4π m Δ v)=6.627×10⁻³⁴4×3.1416×6.8×10⁻⁵, Δ x≥7.76×10⁻³¹ m
  4. The velocity 0.85 m s⁻¹ does not enter: the principle limits the spreads, not the values. (With the form Δ x Δ p≥ h/2π the answer is 1.55×10⁻³⁰ m; the conclusion is the same.)
  5. Scale: 7.76×10⁻³¹ m is 10¹⁵ times smaller than a proton. No instrument can detect it, so the bee has a well-defined trajectory.
  6. Contrast: an electron (m=9.11×10⁻³¹ kg) with the same Δ v has Δ x=5.8×10⁻⁴ m, far larger than an atom. For electrons in atoms the principle replaces orbits by orbitals (probability distributions).

Application. the same relation sets the zero-point energy of a particle in a box and of a vibrating bond: confining a particle to a region Δ x forces a momentum spread and hence a minimum kinetic energy.

Practising this answer? Write it in a Mains test and get it checked by VKC. Civil Services Mains test series · Telegram

Model answer to Q1(d), 2019 Paper I: solution page 6
Solution page 6 of 40