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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper I

Q1(j). Transition elements and CuCl

Question

Define transition elements. Is CuCl a transition metal compound? Justify your answer.

Answer in brief

A transition element has an incomplete d subshell in its atom or can form a cation with an incomplete d subshell. CuCl is a compound of the transition element copper, though Cu(I) itself is d¹⁰.

Key points

  • Copper forms Cu(II), 3d⁹, and therefore qualifies as a transition element.
  • In CuCl, copper is Cu(I), with filled 3d¹⁰. It consequently lacks the unpaired d electrons and ordinary d–d transitions associated with many transition-metal ions.
  • Distinguish classification of the element from the electronic configuration in one compound. A d¹⁰ oxidation state does not reclassify copper as a non-transition element.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(j), 2020 Mains Paper I: solution pages 5 and 6
Solution pages 5 and 6 of 16

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