Q11(b). EMF of Zn | ZnCl₂(m) | AgCl, Ag in terms of γ±
Obtain the expression of e.m.f. (E) of the galvanic cell Zn | ZnCl₂(aq, m) | AgCl, Ag in terms of its standard e.m.f. (E°), the molality (m) of the electrolyte and its mean ionic activity coefficient (γ±).
Model answer
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CoversNernst equationmean ionic activity coefficientZnCl2 cellcell EMF
All parts of Question 11
- 11(a) Correct conditions for chemical equilibrium5 marks
- 11(b) EMF of Zn | ZnCl₂(m) | AgCl, Ag in terms of γ±5 marks
- 11(c) Bond dissociation energy from band convergence10 marks