VKC ScienceChemistry for written exams Telegram

UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper II

Q11(a). Virial expansion and Boyle temperature

Question

Express the van der Waals equation in virial form in molar volume and derive the Boyle temperature.

Answer in brief

Z=1+[b-a/(RT)]/Vₘ+b²/Vₘ²+⋯ and TB=a/(Rb).

Part of VKC Basic

Read the key points and the full model answer with VKC Basic

VKC Basic (₹999 for 6 months) opens every solved answer, the notes, the handbook and the daily answer archive. Every Mains test series includes it.

See what is included Already a member? Sign in

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

The handwritten model answer pages open with the VKC plan.
Read the whole 2020 solution2020 question paper

CoversVirial expansionBoyle temperatureReal gases

All parts of Question 11