Q15(c). Photodimerisation of anthracene: [A₂] independent of [A]
Dimerisation of anthracene (A) in benzene happens by absorption of electromagnetic radiation. The concentration of its dimer at equilibrium, [A₂]eq, is independent of the initial monomer concentration [A] in the higher concentration region. Explain with reason.
Model answer
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Coversphotodimerisationanthracenephotostationary statequantum yield
All parts of Question 15
- 15(a) Rotational constant versus bond length and reduced mass5 marks
- 15(b) CO₂ bending mode: IR active, Raman inactive5 marks
- 15(c) Photodimerisation of anthracene: [A₂] independent of [A]10 marks